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Trees & Capillary
Action
First posted May 6, 2004 Last
updated July 5, 2004

Ever wonder
how a tree as tall as a redwood can get water all the
way from its roots to its top leaves? Water is pretty
heavy, yet the redwood tree moves thousands of gallons
of water (that's 8,000 pounds, or 4 tons) up into its
canopy every day, and it does it without doing any work.
That's pretty amazing! Here is how it works.
(And don't worry, we won't be
too scientific. However, if you want more information,
be sure to read the material at the very bottom of the
page.)

First, you need to
know something about the molecule of water.
Water has a simple molecular structure, H20:
two hydrogen atoms and one oxygen atom. The
way that these atoms are made, and the way
that they join into a molecule of water, makes
the water molecule into a miniature
magnet. The scientists describe this
characteristic of the molecule as being "polar",
but we can think of it as a small magnet.
Have you ever noticed that magnets like to
stick together? So do water molecules. This
is called "molecular cohesion."
These little magnets also like to stick together
when they are on a liquid's surface, which
is called "surface tension",
and is the reason that a raindrop tends to
be round. This also explains why water beads
up when poured on a smooth surface like glass.
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Water
Molecule
oxygen
atom is red
hydrogen atoms are white |
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Water
molecules love some other molecules and hate other
molecules.
Have you ever noticed that magnets like to stick
to other metals? So do water molecules. When water
molecules stick to other molecules that are also
little magnets, it is called "molecular
adhesion." This explains why it
is easy to clean up spilled water with a paper
towel: the water molecule's little magnets like
to stick to the cellulose molecules of the paper,
which are also like little magnets. Water molecules
will stick to any other molecules that are like
little magnets (polar), but do not like to get
involved with any molecules that hate little magnets
(nonpolar), like oil. Oil and water don't mix,
right? That is why you have to shake the salad
dressing real hard before you pour it: the oil
molecules hate the water little magnets.
Paper towels are made out of trees, and trees
are made out of cellulose. The leaves make molecules
of sugar out of sunlight, water, and carbon dioxide,
then combine the sugars into huge sugar chains.
These sugar chain molecules are called cellulose.
This name comes from the fact that the plant material
is made of cells, and the "-ose" word
ending means "sugar". Cellulose is also
a great magnet (polar molecule), so water sticks
to cellulose just like a magnet to the refrigerator
door!
Now that we know a bit about water molecules,
let's look at how water acts in a little tube. |

Water
Molecules
bonded
to paper towel |
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| Water
loves to rise in a tube

Meniscus shown in blue
water molecules want to stick together and stick
to side
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Have you ever noticed that water
in a glass tends to hug the sides and even stick
up above the water's surface? The edge of the
water that sticks up above the water's surface
is called a "meniscus."
When you put a small tube into water, the water
likes to stick to each side, with a meniscus on
each side. If the tube is so skinny that the meniscus
on one side can touch the meniscus on the other
side, the water will rise up the tube (each meniscus
wants to go up the side, and they chase each other).
This is called "capillary action."
The redwood tree's trunk is made up of millions
of little bitty tubes (xylem),
and these tubes are made of cellulose. The water
molecules like to stick together and like to stick
to the walls of the tubes of cellulose, so they
rise up the tubes by capillary action. All the
way to the top!
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The water pressure decreases as
it rises up the tree. This is because the capillary
action is fighting the weight of the water. Although
the xylem tube is very thin, and therefore the
weight of the water is very low, it is not zero.
Eventually, the effects of gravity on the water
starts to equal the effects of capillary action.
Scientists have found that the pressure inside
the xylem decreases with the height of the tree,
and similarly, the size of the redwood leaves
decreases with the decrease in pressure. (See
an excellent article in the San
Francisco Chronicle, the source of
the illustration to the right.)
Scientists Dr. George W. Koch of Northern Arizona
University, Dr. Gregory M. Jennings of Humboldt
State in Arcata, California, and Dr. Stephen D.
Davis of Pepperdine University in Malibu, California,
have studied the water pressure inside a coast
redwood. They studied the correlations among the
tree's height, its internal water pressure, leaf
size, photosynthesis and other factors. Dr. Koch
and his colleagues have concluded that no existing
species of tree can grow higher than 130 meters
(427 feet).
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Redwood
Tree and Leave Size
The leaves are smaller at the top of the tree
(graphic modified from the SF
Chronicle, see reference in text to left) |

A More Scientific Treatment
Capillary action is a physical effect caused by the
interactions of a liquid with the walls of a thin tube.
The capillary effect is a function of the ability of
the liquid to wet a particular material. Capillary action
is important for moving water (and all of the things
that are dissolved in it) around. It is defined as the
movement of water within the spaces of a porous material
due to the forces of adhesion (hydrogen bonding between
unlike atoms), cohesion (hydrogen bonding between like
atoms), and surface tension (tendency caused by hydrogen
bonding for water to be attracted to itself and away
from other materials).
| Water climbs up a thin glass or cellulose
tube because of the strong hydrogen-bonding interactions
between the water and the oxygens (and terminal
hydrogens) at the surface of the glass (SiO2;
surface oxygens are typically bonded to hydrogen)
or the cellulose (beta glucose chains, with hydroxyl
side chains on every other molecule oriented to
one side). |
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| The energetic gain from the new intermolecular
interactions must be balanced against gravity, which
attempts to pull the liquid back down. Therefore,
the narrower the tube, the higher the liquid will
climb, because a narrow column of liquid weighs
less than a thick one. The xylem tubes are extremely
small, on the order of 25 micrometers. The equation
for determining the height of the capillary action,
with water in air, is h = 0.3 / d, where h is the
height of rise, and d is the diameter of the capillary
tube, when both are measured in centimeters.Incidentally,
cellulose is probably the most abundant organic
molecule in the universe, with an estimated 100
billion pounds produced by plants annually. |
References
Transport
of water and minerals in plants This is
a really great site that goes into the subject of xylem
flow, transpiration, and the scientific evidence for
the discussion above.
Xylem
This site shows microscope slides of xylem.

Acknowledgments
The water molecules were taken from
a chemistry website and modified in Photoshop; molecular
diagrams by Dr. Nelson. The cellulose model is from
the carbohydrates and biology section of the Regional
Coverage Network.

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